Telluronium Ions as σ‐Acceptor Ligands1. Issue 14 (18th February 2013)

• Record Type: Journal Article
• Authors: Lin, Tzu‐Pin; Gabbaï, François P.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 14(2013)
• Page Start: 3864
• Page End: 3868
• Publication Date: 2013-02-18
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201300337
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A duel between lone pairs:</bold> A telluronium cation has been successfully installed in the coordination sphere of a palladium(II) complex. Despite the presence of a lone pair centered on the Group 16 element, the telluronium ion acts as a Z‐ligand and accepts a d‐electron pair from the palladium atom.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1x47k9km" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>