Three‐Dimensional Structural Analysis of MgO‐Supported Osmium Clusters by Electron Microscopy with Single‐Atom Sensitivity1. Issue 20 (16th April 2013)

• Record Type: Journal Article
• Authors: Aydin, Ceren; Kulkarni, Apoorva; Chi, Miaofang; Browning, Nigel D.; Gates, Bruce C.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 20(2013)
• Page Start: 5262
• Page End: 5265
• Publication Date: 2013-04-16
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201300238
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Size, shape, nuclearity</bold>: Aberration‐corrected scanning transmission electron microscopy was used to determine the 3D structures of MgO‐supported Os₃, Os₄, Os₅, and Os₁₀ clusters, which have structures nearly matching those of osmium carbonyl compounds with known crystal structures. The samples are among the best‐defined supported catalysts.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1zsxhjkg" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>