Mixed‐Linker Hybrid Superpolyhedra for the Production of a Series of Large‐Pore Iron(III) Carboxylate Metal–Organic Frameworks1. Issue 19 (3rd April 2013)

• Record Type: Journal Article
• Authors: Chevreau, Hubert; Devic, Thomas; Salles, Fabrice; Maurin, Guillaume; Stock, Norbert; Serre, Christian
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 19(2013)
• Page Start: 5056
• Page End: 5060
• Publication Date: 2013-04-03
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201300057
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>It's all in the mix</bold>! Metal–organic frameworks (MOFs) were constructed from iron(III) trimers and mixtures of di‐ and tricarboxylate linkers. The dicarboxylate linker determined the size and shape of the pores in one series of materials with an interwoven structure and also enabled the introduction of different functionalities. Another mesoporous iron(III) MOF based on hybrid supertetrahedra had an extended β‐cristobalite structure (see picture).<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1zsxk6t4" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>