Rhodium(III)‐Catalyzed CC Coupling between Arenes and Aziridines by CH Activation1. Issue 9 (31st January 2013)

• Record Type: Journal Article
• Authors: Li, Xingwei; Yu, Songjie; Wang, Fen; Wan, Boshun; Yu, Xinzhang
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 9(2013)
• Page Start: 2577
• Page End: 2580
• Publication Date: 2013-01-31
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201209887
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Making CC from CH</bold>: [{RhCp*Cl₂}₂]/AgSbF₆ (Cp*=pentamethylcyclopentadienyl) can regioselectively catalyze the CC coupling of arenes with aziridines by a CH activation pathway. An eight‐membered rhodacyclic intermediate resulting from the insertion of the RhC bond into the aziridine was isolated.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1v49fkxg" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>