Generation of a Dynamic System of Three‐Dimensional Tetrahedral Polycatenanes1. Issue 22 (18th April 2013)

• Record Type: Journal Article
• Authors: Black, Samuel P.; Stefankiewicz, Artur R.; Smulders, Maarten M. J.; Sattler, Dominik; Schalley, Christoph A.; Nitschke, Jonathan R.; Sanders, Jeremy K. M.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 22(2013)
• Page Start: 5749
• Page End: 5752
• Publication Date: 2013-04-18
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201209708
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Seven of the best</bold>: A dynamic combinatorial library of polycatenated tetrahedra was prepared by complexation between a dynamic Fe₄L₆ tetrahedral cage, constructed from ligands containing an electron‐deficient naphthalenediimide core, and an electron‐rich aromatic crown ether, 1, 5‐dinaphtho[38]crown‐10. The highest order species in the library is the tetrahedral [7]catenane.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg20p494kj" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>