The Oligomerization of Phosphinoborane by Titanium Complexes1. Issue 19 (10th April 2013) - Thoms, Christine
Abstract The PB chain gang: The reactions of an acetylene complex of titanocene with the parent phosphinoborane stabilized only by a Lewis base lead to novel phosphinoborane oligomers coordinated by {Cp2Ti} complex fragments. Depending on the reaction conditions (temperature and stoichiometry), unprecedented oligomeric chains of phosphinoborane are obtained by dehydro‐oligomerization and PP coupling reactions. btmsa = bis(trimethylsilyl)acetylene.