Ferrocene and Pentaphosphaferrocene: A Comparative Study Regarding Redox Chemistry1. Issue 10 (31st January 2013)

• Record Type: Journal Article
• Authors: Butovskiy, Mikhail V.; Balázs, Gábor; Bodensteiner, Michael; Peresypkina, Eugenia V.; Virovets, Alexander V.; Sutter, Jörg; Scheer, Manfred
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 10(2013)
• Page Start: 2972
• Page End: 2976
• Publication Date: 2013-01-31
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201209329
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Pentaphosphaferrocene redox chemistry</bold>: Unprecedented dianionic and PP coupled and monomeric products are obtained by the reduction of pentaphosphaferrocene with KH or K metal, whereas by oxidation a PP coupled P₁₀²⁺ ligand coordinated to two Cp*Fe units is obtained. The redox behavior clearly distinguishes pentaphosphaferrocene from its organometallic relative, ferrocene.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1ts9s8rc" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>