Bis(tetrasulfato)palladate, [Pd(S4O13)2]2−1. Issue 9 (29th January 2013)

• Record Type: Journal Article
• Authors: Bruns, Jörn; Klüner, Thorsten; Wickleder, Mathias S.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 9(2013)
• Page Start: 2590
• Page End: 2592
• Publication Date: 2013-01-29
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201209346
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>SOS</bold>: The first coordination compound containing polysulfate ligands was obtained under harsh conditions from the reaction of K₂[PdCl₄] and SO₃. The compound contains a Pd²⁺ ion coordinated by two chelating tetrasulfate anions (see structure, Pd red, S yellow, O blue), which leads to a significant stabilization of the polysulfate anions compared to their uncoordinated analogues.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1v49fkkz" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>