Discovering More Non‐Innocence: Triazenido versus Triazenyl Radical Ligand Function, and a Comment on [NO2]n as a "Suspect" Ligand1. Issue 17 (20th March 2013)

• Record Type: Journal Article
• Authors: Ehret, Fabian; Bubrin, Martina; Záliš, Stanislav; Kaim, Wolfgang
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 17(2013)
• Page Start: 4673
• Page End: 4675
• Publication Date: 2013-03-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201209260
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>The unusual suspects</bold>: Depending on co‐ligands L_{<italic>n</italic>} and the effects of substituents (R), the well‐known triazenides [N(NR)₂]⁻ may act as EPR detectable coordinated triazenyl ligands, [N(NR)₂]^. (see scheme). They are thus new non‐innocent ligands and are related to the hitherto unused non‐innocent nitrogen dioxide ligand, [NO₂]^..<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1xps7mbc" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>