[Au14(PPh3)8(NO3)4]: An Example of a New Class of Au(NO3)‐Ligated Superatom Complexes1. Issue 12 (18th February 2013)

• Record Type: Journal Article
• Authors: Gutrath, Benjamin S.; Oppel, Iris M.; Presly, Oliver; Beljakov, Igor; Meded, Velimir; Wenzel, Wolfgang; Simon, Ulrich
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 12(2013)
• Page Start: 3529
• Page End: 3532
• Publication Date: 2013-02-18
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201208681
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Golden beauty</bold>: For the first time a ligand‐stabilized Au₁₄ cluster has been examined. The structure of this superatom complex bears several impressive and unique features, which will further support the understanding of certain guiding principles for molecular‐precision synthesis and functionalization of ultrasmall nanoparticles.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1v78m43q" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>