A Generic One‐Pot Route to Acyclic Two‐Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene1. Issue 2 (20th November 2012)

• Record Type: Journal Article
• Authors: Protchenko, Andrey V.; Schwarz, Andrew D.; Blake, Matthew P.; Jones, Cameron; Kaltsoyannis, Nikolas; Mountford, Philip; Aldridge, Simon
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 2(2013)
• Page Start: 568
• Page End: 571
• Publication Date: 2012-11-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201208554
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Si in sight</bold>: A one‐pot, single‐step synthesis of an acyclic silylsilylene, Si{Si(SiMe₃)₃}{N(SiMe₃)Dipp} (Dipp=2, 6‐<italic>i</italic>Pr₂C₆H₃), from a silicon(IV) starting material is reported, together with evidence for a mechanism involving alkali metal silylenoid intermediates.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1p994jmt" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>