Glaser Coupling at Metal Surfaces1. Issue 14 (19th February 2013)

• Record Type: Journal Article
• Authors: Gao, Hong‐Ying; Wagner, Hendrik; Zhong, Dingyong; Franke, Jörn‐Holger; Studer, Armido; Fuchs, Harald
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 14(2013)
• Page Start: 4024
• Page End: 4028
• Publication Date: 2013-02-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201208597
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>On‐surface synthesis</bold> is a promising approach for constructing covalently bound nanostructures. However, the number of reliable chemical reactions suitable for on‐surface chemistry is very limited. Arylalkynes can be coupled at various surfaces in a novel 2D Glaser coupling (see picture). This approach can be used for constructing conjugated materials directly on surfaces.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1x47kc97" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>