Decarboxylative Cross‐Coupling of Mesylates Catalyzed by Copper/Palladium Systems with Customized Imidazolyl Phosphine Ligands1. Issue 10 (5th February 2013)

• Record Type: Journal Article
• Authors: Song, Bingrui; Knauber, Thomas; Gooßen, Lukas J.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 10(2013)
• Page Start: 2954
• Page End: 2958
• Publication Date: 2013-02-05
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201208025
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>The activation of the inert CO bonds</bold> in mesylates through the use of a new class of imidazolyl phosphines allows the decarboxylative coupling of aryl mesylates as well as polysubstituted alkenyl mesylates. Variation of the ligands leads to two complementary methods providing the corresponding biaryls and polysubstituted olefins in good yields.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1ts9s5mm" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>