Dynamically Deformable Cube‐like Hydrogen‐Bonding Networks in Water‐Responsive Diamondoid Porous Organic Salts1. Issue 6 (10th January 2013)

• Record Type: Journal Article
• Authors: Yamamoto, Atsushi; Hamada, Tomoya; Hisaki, Ichiro; Miyata, Mikiji; Tohnai, Norimitsu
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 6(2013)
• Page Start: 1709
• Page End: 1712
• Publication Date: 2013-01-10
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201208153
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Just add water</bold>: A cube‐like hydrogen‐bonding network in a fluorescent supramolecular cluster dynamically deforms upon the specific addition of a water molecule. The deformation is amplified through the conformational change of the cluster to result in the transformation of host frameworks. This transformation provides water‐responsive guest‐exclusion and fluorescent‐modulation behaviors.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1v48gghb" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>