Broadband Inversion PELDOR Spectroscopy with Partially Adiabatic Shaped Pulses1. Issue 12 (19th February 2013)

• Record Type: Journal Article
• Authors: Spindler, Philipp E.; Glaser, Steffen J.; Skinner, Thomas E.; Prisner, Thomas F.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 12(2013)
• Page Start: 3425
• Page End: 3429
• Publication Date: 2013-02-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201207777
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Distance and spins</bold>: A new broadband, frequency‐selective inversion pulse has been devised for pulsed electron–electron double resonance (PELDOR) spectroscopy, a unique method used to determine distance distributions between two or more paramagnetic centers 2–10 nm apart. The PELDOR modulation depth can be increased by substituting the rectangular pump pulse by a shaped pulse.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1v78m2t8" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>