"On Water": Efficient Iron‐Catalyzed Cycloaddition of Aziridines with Heterocumulenes1. Issue 2 (20th November 2012)

• Record Type: Journal Article
• Authors: Sengoden, Mani; Punniyamurthy, Tharmalingam
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 2(2013)
• Page Start: 572
• Page End: 575
• Publication Date: 2012-11-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201207746
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>In suspension</bold>: The reaction of aziridines with heterocumulenes in the presence of Fe(NO₃)₃⋅9 H₂O in aqueous suspension provides access to functionalized five‐membered heterocycles in good to high yields. This protocol has a wide substrate scope, is simple, and uses a nontoxic and cheap catalyst.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1p994r7v" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>