Characterization of a Macrocyclic end‐on Peroxido Copper Complex1. Issue 3 (23rd November 2012)

• Record Type: Journal Article
• Authors: Hoppe, Tobias; Schaub, Stefan; Becker, Jonathan; Würtele, Christian; Schindler, Siegfried
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 3(2013)
• Page Start: 870
• Page End: 873
• Publication Date: 2012-11-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201205663
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Thirty years on</bold>: The dinuclear copper peroxido complex [(tet b)CuO₂Cu(tet b)]²⁺ has been structurally characterized (see picture: Cu yellow, O red, N pink; tet b=<italic>rac</italic>‐5, 5, 7, 12, 12, 14‐hexamethyl‐1, 4, 8, 11‐tetraazacyclotetradecane). This complex is quite persistent in solution at room temperature and is the first example of a structurally characterized copper dioxygen adduct complex with a macrocyclic ligand based on earlier studies by Valentine et al.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1p9wb7dc" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>