Electrochemical Synthesis of Transparent, Amorphous, C60‐Rich, Photoactive, and Low‐Doped Film with an Interconnected Structure. Issue 12 (29th January 2013)

• Record Type: Journal Article
• Authors: Li, Mao; Ishihara, Shinsuke; Ohkubo, Kei; Liao, Meiyong; Ji, Qingmin; Gu, Cheng; Pan, Yuyu; Jiang, Xiangfen; Akada, Misaho; Hill, Jonathan P.; Nakanishi, Takashi; Ma, Yuguang; Yamauchi, Yusuke; Fukuzumi, Shunichi; Ariga, Katsuhiko
• Is Part Of: Small. Volume 9:Issue 12(2013:Jun.)
• Page Start: 2064
• Page End: 2068
• Publication Date: 2013-01-29
• Subjects: Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.201202680
• Languages: English
• ISSNs: 1613-6810

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>An electrochemical synthesis is developed through quantitative electrochemical reaction of <italic>N</italic>‐alkylcarbazole leading to a novel class of structurally interconnected high‐C₆₀ content (60 wt%) polymer films with negligible doping and intrinsic physicochemical properties of pure C₆₀. This strategy allows preparation of previously unavailable low‐doped fullerene‐containing non‐conjugated polymers and broadens the potential applications of electrochemical synthesis for controlled polymer film structures. <boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg224zp5f2" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>