Formation of Integral Asymmetric Membranes of AB Diblock and ABC Triblock Copolymers by Phase Inversion. Issue 7 (7th February 2013)

• Record Type: Journal Article
• Authors: Jung, Adina; Filiz, Volkan; Rangou, Sofia; Buhr, Kristian; Merten, Petra; Hahn, Janina; Clodt, Juliana; Abetz, Clarissa; Abetz, Volker
• Is Part Of: Macromolecular rapid communications. Volume 34:Issue 7(2013:Apr.)
• Page Start: 610
• Page End: 615
• Publication Date: 2013-02-07
• Subjects: Macromolecules -- Periodicals; Polymers -- Periodicals; Chemistry -- Periodicals; 547.705
• DOI: 10.1002/marc.201200770
• Languages: English
• ISSNs: 1022-1336

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The formation of integral asymmetric membranes from ABC triblock terpolymers by non‐solvent‐induced phase separation is shown. They are compared with the AB diblock copolymer precursors. Triblock terpolymers of polystyrene‐<italic>block</italic>‐poly(2‐vinylpyridine)‐<italic>block</italic>‐poly(ethylene oxide) (PS‐<italic>b</italic>‐P2VP‐<italic>b</italic>‐PEO) with two compositions are investigated. The third block supports the formation of a membrane in a case, where the corresponding diblock copolymer does not form a good membrane. In addition, the hydrophilicity is increased by the third block and due to the hydroxyl group the possibility of post‐functionalization is given. The morphologies are imaged by scanning electron microscopy. The influence of the PEO on the membrane properties is analyzed by water flux, retention, and dynamic contact angle measurements.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1x6hdnhp" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>