Preparation of a Spontaneously Resolved Chiral Fluorescent System Containing 4‐(2‐Arylethynyl)benzoic Acid. Issue 8 (11th June 2013)

• Record Type: Journal Article
• Authors: Taniguchi, Naoya; Shimomaki, Ryutaro; Amako, Tomoyuki; Sato, Tomohiro; Tokutome, Hayato; Tajima, Nobuo; Kuroda, Reiko; Fujiki, Michiya; Imai, Yoshitane
• Is Part Of: Asian journal of organic chemistry. Volume 2:Issue 8(2013:Aug.)
• Page Start: 681
• Page End: 687
• Publication Date: 2013-06-11
• Subjects: Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; 547.005
• DOI: 10.1002/ajoc.201300084
• Languages: English
• ISSNs: 2193-5807

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A spontaneously resolved chiral fluorescent system was prepared from achiral 4‐(2‐arylethynyl)benzoic acid and racemic (<italic>rac</italic>)‐1‐phenylethylamine. Although functional chiral organic materials are usually prepared from chiral molecules, the chiral organic fluorophore described herein is successfully generated from achiral and racemic molecules to form a system that emits circularly polarized luminescence (CPL) in the solid state.</p> </abstract>