Core/Shell PBA/PMMA‐PGMA Nanoparticles to Enhance the Impact Resistance of UV‐Cured Epoxy Systems. Issue 1 (24th April 2012)

• Record Type: Journal Article
• Authors: Naguib, Mohamed; Grassini, Sabrina; Sangermano, Marco
• Is Part Of: Macromolecular materials and engineering. Volume 298:Issue 1(2013:Jan.)
• Page Start: 106
• Page End: 112
• Publication Date: 2012-04-24
• Subjects: Plastics -- Periodicals; Polymers -- Periodicals; Polymerization -- Periodicals; 547.705
• DOI: 10.1002/mame.201200001
• Languages: English
• ISSNs: 1438-7492

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Crosslinked core/shell PBA/PMMA‐PGMA particles are prepared by emulsion polymerization and dispersed into a UV‐curable cycloaliphatic epoxy resin in the range of 5–15 wt%. The presence of the particles does not significantly affect the UV curing process: a slight decrease of final epoxy group conversion is attributed to an increase in the viscosity when CS‐GMA is added to the photocurable formulation and to an enhanced vitrification effect. The presence of the particles does not modify the <italic>T</italic>_g of the cured materials, while an enhancement of impact resistance is observed that does not depend on the particle content. FESEM micrographs for epoxy reinforced with core/shell particles indicate a plastic void growth of the epoxy polymer and shear yielding toughening mechanism.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1qc08qn2" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>