Compressed Exponential Response Function Arising From a Continuous Distribution of Gaussian Decays – Distribution Characteristics. Issue 7 (31st January 2013)

• Record Type: Journal Article
• Authors: Hansen, Eddy W.; Gong, Xiaoliang; Chen, Qun
• Is Part Of: Macromolecular chemistry and physics. Volume 214:Issue 7(2013:Apr.)
• Page Start: 844
• Page End: 852
• Publication Date: 2013-01-31
• Subjects: Polymers -- Periodicals; Polymerization -- Periodicals; Synthetic products -- Periodicals; Macromolecules -- Periodicals; 547.7
• DOI: 10.1002/macp.201200715
• Languages: English
• ISSNs: 1022-1352

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A compressed exponential function (CEF) is shown to be represented by a distribution of Gaussian functions. The properties and characteristics of the distribution are detailed and discussed, and are illustrated with reference to the change in the NMR spectroscopy proton Hahn echo relaxation response that takes place in a composite material (prepared by melt compounding a mixture of graphite nanoparticles and pyromellitic anhydride modified polypropylene carbonate (PPC)) during aging at 90 °C. The results show that both the width and the average value of the spin‐spin relaxation rate distribution decrease during aging, suggesting that the molecular motion becomes less constrained and less heterogeneous.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1x6h5np2" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>