Arene CH Bond Functionalization Coupling with Cyclization of Allenes. Issue 10 (12th July 2013)

• Record Type: Journal Article
• Authors: Zeng, Rong; Ye, Juntao; Fu, Chunling; Ma, Shengming
• Is Part Of: Advanced synthesis & catalysis. Volume 355:Issue 10(2013)
• Page Start: 1963
• Page End: 1970
• Publication Date: 2013-07-12
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201300408
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Under the catalysis of a rhodium(III) complex, the cyclization of 2, 3‐allenols was most probably initiated with the CH bond functionalization of <italic>N</italic>‐methoxybenzamides using the tetramethylcyclopentadiene anion (C₅Me₄⁻) as ligand, affording differently substituted 2, 5‐dihydrofuran derivatives. Highly efficient axial‐to‐central chirality transfer has been observed.</p> </abstract>