Dehydrogenation of Dodecahydro‐N‐ethylcarbazole on Pt(111). Issue 6 (14th May 2013)

• Record Type: Journal Article
• Authors: Gleichweit, Christoph; Amende, Max; Schernich, Stefan; Zhao, Wei; Lorenz, Michael P. A.; Höfert, Oliver; Brückner, Nicole; Wasserscheid, Peter; Libuda, Jörg; Steinrück, Hans‐Peter; Papp, Christian
• Is Part Of: ChemSusChem. Volume 6:Issue 6(2013:Jun.)
• Page Start: 974
• Page End: 977
• Publication Date: 2013-05-14
• Subjects: Green chemistry -- Periodicals; Sustainable engineering -- Periodicals; Chemistry -- Periodicals; Chemical engineering -- Periodicals; 660
• DOI: 10.1002/cssc.201300263
• Languages: English
• ISSNs: 1864-5631

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Sloshing hydrogen:</bold> Liquid organic hydrogen carriers are high‐boiling organic molecules, which can be reversibly hydrogenated and dehydrogenated in catalytic processes and are, therefore, a promising chemical hydrogen storage material. One of the promising candidates is the pair <italic>N</italic>‐ethylcarbazole/perhydro‐<italic>N</italic>‐ethylcarbazole (NEC/H₁₂‐NEC). The dehydrogenation and possible side reactions on a Pt(111) surface are evaluated in unprecedented detail.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg21fq4c57" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>