Ceria‐Catalyzed Conversion of Carbon Dioxide into Dimethyl Carbonate with 2‐Cyanopyridine. Issue 8 (25th June 2013)

• Record Type: Journal Article
• Authors: Honda, Masayoshi; Tamura, Masazumi; Nakagawa, Yoshinao; Sonehara, Satoru; Suzuki, Kimihito; Fujimoto, Ken‐ichiro; Tomishige, Keiichi
• Is Part Of: ChemSusChem. Volume 6:Issue 8(2013:Aug.)
• Page Start: 1341
• Page End: 1344
• Publication Date: 2013-06-25
• Subjects: Green chemistry -- Periodicals; Sustainable engineering -- Periodicals; Chemistry -- Periodicals; Chemical engineering -- Periodicals; 660
• DOI: 10.1002/cssc.201300229
• Languages: English
• ISSNs: 1864-5631

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>DMC run:</bold> Carbon dioxide can be converted into dimethyl carbonate in a reaction system involving 2‐cyanopyridine as a dehydration agent, catalyzed by CeO₂. Regeneration of the coproduct 2‐picolinamide can be achieved over a Na₂O/SiO₂ catalyst. As a whole, the system servest to react carbon dioxide with methanol to produce dimethyl carbonate.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36t01m7w" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>