Self‐Assembly and Visible‐Light Photocatalytic Properties of W/Nb Mixed‐Addendum Polyoxometalate and Transition‐Metal Cations. Issue 8 (11th June 2013)

• Record Type: Journal Article
• Authors: Huang, Peng; Qin, Chao; Wang, Xin‐Long; Sun, Chun‐Yi; Jiao, Yan‐Qing; Xing, Yan; Su, Zhong‐Min; Shao, Kui‐Zhan
• Is Part Of: ChemPlusChem. Volume 78:Issue 8(2013:Aug.)
• Page Start: 775
• Page End: 779
• Publication Date: 2013-06-11
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cplu.201300175
• Languages: English
• ISSNs: 2192-6506

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Making light work</bold>: Three novel W/Nb mixed‐addendum polyoxometalates, which all contain the {SiNb₃W₉O₄₀} cluster, have been synthesized by conventional aqueous methods. Visible‐light photocatalytic H₂ evolution activity (see figure) was observed for two of the compounds, with H₂PtCl₆ as a cocatalyst and triethylamine as a sacrificial electron donor.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36svhxrc" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>