Enantioselective Rhodium‐Catalyzed Addition of Arylboronic Acids to Trifluoromethyl Ketones. Issue 7 (30th April 2013)

• Record Type: Journal Article
• Authors: Luo, Renshi; Li, Ke; Hu, Yuling; Tang, Wenjun
• Is Part Of: Advanced synthesis & catalysis. Volume 355:Issue 7(2013)
• Page Start: 1297
• Page End: 1302
• Publication Date: 2013-04-30
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201201125
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A new <italic>C</italic>₂‐symmetrical, chiral bisphosphorus ligand proved to be efficient for the rhodium‐catalyzed nucleophilic addition of arylboronic acids to trifluoromethyl ketones, providing a series of chiral trifluoromethyl‐substituted tertiary alcohols in high yields (up to 93%) and excellent enantioselectivities (&gt;99%).</p> </abstract>