Gold‐Catalyzed Highly Diastereoselective Synthesis of Functionalized 3, 4‐Disubstituted Butyrolactams via Phosphatyloxy or Carbonate Double Migrations. Issue 10 (12th July 2013)

• Record Type: Journal Article
• Authors: Yang, Weibo; Yu, Yang; Zhang, Tuo; Hansmann, Max M.; Pflästerer, Daniel; Hashmi, A. Stephen K.
• Is Part Of: Advanced synthesis & catalysis. Volume 355:Issue 10(2013)
• Page Start: 2037
• Page End: 2043
• Publication Date: 2013-07-12
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201300158
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A gold‐catalyzed highly diastereoselective synthesis of functionalised 3, 4‐disubstituted butyrolactams <italic>via</italic> phosphatyloxy or carbonate double migrations is reported, which is proposed to proceed by a tandem 1, 3‐phosphatyloxy or carbonate migration and a "long‐range" 1, 5‐phosphatyloxy or carbonate migration, which overall corresponds to a formal 1, 6‐migration.</p> </abstract>