Room Temperature Palladium‐Catalyzed Decarboxylative Acyl/Aroylation using [Fe(III)(EDTA)(η2‐O2)]3− as Oxidant at Biological pH. Issue 4 (22nd February 2013)

• Record Type: Journal Article
• Authors: Sharma, Sugandha; Khan, Imran A.; Saxena, Anil K.
• Is Part Of: Advanced synthesis & catalysis. Volume 355:Issue 4(2013)
• Page Start: 673
• Page End: 678
• Publication Date: 2013-02-22
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201201085
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The purple‐coloured iron peroxo complex [Fe(III)EDTA(η²‐O₂)]³⁻ as a novel reagent system for Pd‐catalyzed decarboxylative <italic>ortho</italic>‐acylation of acetanilides with α‐oxocarboxylic acids at room temperature in aqueous media has been realized. This reaction provides an effective access to <italic>ortho</italic>‐acylacetanilides under mild conditions.</p> </abstract>