ChemInform Abstract: Ambivalent Reactivity Modes of β‐Chlorovinyl Ketones: Electrophilic Lithium [3]Cumulenolates from Soft Vinyl Enolization Strategy. Issue 51 (17th December 2013)

Record Type:
Journal Article
Title:
ChemInform Abstract: Ambivalent Reactivity Modes of β‐Chlorovinyl Ketones: Electrophilic Lithium [3]Cumulenolates from Soft Vinyl Enolization Strategy. Issue 51 (17th December 2013)
Main Title:
ChemInform Abstract: Ambivalent Reactivity Modes of β‐Chlorovinyl Ketones: Electrophilic Lithium [3]Cumulenolates from Soft Vinyl Enolization Strategy.
Authors:
Kim, Hun Young
Rooney, Edward Oscar
Meury, Raymond Phillip
Oh, Kyungsoo
Abstract:
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Treatment of β‐chlorovinyl ketones with NEt<sub>3</sub> and LiClO<sub>4</sub> or LiBr results in formation of electrophilic lithium cumulenolates which smoothly react with nucleophiles such as another cumulenolate or ketimines to afford vinyl allenones like (II) or pyrrolidines of type (IV)/(VII) in a stereoselective manner.</p> </abstract>
Is Part Of:
ChemInform. Volume 44:Issue 51(2013)
Journal:
ChemInform
Issue:
Volume 44:Issue 51(2013)
Issue Display:
Volume 44, Issue 51 (2013)
Year:
2013
Volume:
44
Issue:
51
Issue Sort Value:
2013-0044-0051-0000
Page Start:
no
Page End:
no
Publication Date:
2013-12-17
Subjects:
Chemistry -- Abstracts -- Periodicals
540.5
Journal URLs:
http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1522-2667 ↗
http://onlinelibrary.wiley.com/ ↗
DOI:
10.1002/chin.201351032 ↗
Languages:
English
ISSNs:
0931-7597
Deposit Type:
Legaldeposit
View Content:
Available online (eLD content is only available in our Reading Rooms) ↗
Physical Locations:
British Library DSC - 3158.195000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store
Ingest File:
4103.xml