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ChemInform Abstract: Diastereo‐ and Enantioselective Nitro‐Mannich Reaction of α‐Substituted Nitroacetates to N‐Phosphoryl Imines Catalyzed by cinchona Alkaloid Thiourea Organocatalysts. Issue 36 (15th August 2013)
Record Type:
Journal Article
Title:
ChemInform Abstract: Diastereo‐ and Enantioselective Nitro‐Mannich Reaction of α‐Substituted Nitroacetates to N‐Phosphoryl Imines Catalyzed by cinchona Alkaloid Thiourea Organocatalysts. Issue 36 (15th August 2013)
Main Title:
ChemInform Abstract: Diastereo‐ and Enantioselective Nitro‐Mannich Reaction of α‐Substituted Nitroacetates to N‐Phosphoryl Imines Catalyzed by cinchona Alkaloid Thiourea Organocatalysts.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The presented method is highly tolerable to functionalized N‐phosphoryl imines and provides a reliable synthetic route to the corresponding β‐nitro ethylphosphoramidates (III) with adjacent quaternary and tertiary chiral centers in high enantio‐ and diastereoselectivity.</p> </abstract>