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ChemInform Abstract: Carbolithiation of S‐Alkenyl‐N‐aryl thiocarbamates: Carbanion Arylation in a Connective Route to Tertiary Thiols. Issue 33 (25th July 2013)
Record Type:
Journal Article
Title:
ChemInform Abstract: Carbolithiation of S‐Alkenyl‐N‐aryl thiocarbamates: Carbanion Arylation in a Connective Route to Tertiary Thiols. Issue 33 (25th July 2013)
Main Title:
ChemInform Abstract: Carbolithiation of S‐Alkenyl‐N‐aryl thiocarbamates: Carbanion Arylation in a Connective Route to Tertiary Thiols.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>S‐Alkenyl‐N‐arylthiocarbamates undergo carbolithiation with a range of organolithium reagents, generating benzyllithium intermediates in a stereospecific manner which may undergo N to C aryl migration to yield thiocarbamates with tertiary substituents.</p> </abstract>