<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The new compound [enH<sub>2</sub>]<sub>8</sub> [Fe<sub>4</sub>(en)(α‐GeW<sub>9</sub>O<sub>34</sub>)<sub>2</sub>] [Fe<sub>4</sub>(en)<sub>2</sub> (α‐GeW<sub>9</sub>O<sub>34</sub>)<sub>2</sub>] ·en·14H<sub>2</sub>O is hydrothermally synthesized from a mixture of K<sub>8</sub>Na<sub>2</sub>[A‐α‐GeW<sub>9</sub>O<sub>34</sub>], Ce(NH<sub>4</sub>)<sub>4</sub>(SO<sub>4</sub>)<sub>4</sub>, FeCl<sub>3</sub>, en, and H<sub>2</sub>O (autoclave, 160 °C, 6 d, 25% yield).</p> </abstract>