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ChemInform Abstract: CaF2‐Catalyzed SN2‐type Chlorodehydroxylation of Chiral Secondary Alcohols with Thionyl Chloride: A Practical and Convenient Approach for the Preparation of Optically Active Chloroalkanes. Issue 32 (18th July 2013)
Record Type:
Journal Article
Title:
ChemInform Abstract: CaF2‐Catalyzed SN2‐type Chlorodehydroxylation of Chiral Secondary Alcohols with Thionyl Chloride: A Practical and Convenient Approach for the Preparation of Optically Active Chloroalkanes. Issue 32 (18th July 2013)
Main Title:
ChemInform Abstract: CaF2‐Catalyzed SN2‐type Chlorodehydroxylation of Chiral Secondary Alcohols with Thionyl Chloride: A Practical and Convenient Approach for the Preparation of Optically Active Chloroalkanes.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The SOCl<sub>2</sub>/CaF<sub>2</sub> system shows superior properties compared to SOCl<sub>2</sub>/Py with regards to higher yields and enantioselectivity and is found to be suitable for large scale preparations.</p> </abstract>