ChemInform Abstract: A Polyoxometalate‐Based Single‐Molecule Magnet with a Mixed‐Valent {MnIV2MnIII6Mn II4} Core. Issue 22 (13th May 2013)

• Record Type: Journal Article
• Authors: Zhang, Zhi‐Ming; Yao, Shuang; Li, Yang‐Guang; Wu, Hai‐Hong; Wang, Yong‐Hui; Rouzieres, Mathieu; Clerac, Rodolphe; Su, Zhong‐Min; Wang, En‐Bo
• Is Part Of: ChemInform. Volume 44:Issue 22(2013)
• Page Start: no
• Page End: no
• Publication Date: 2013-05-13
• Subjects: Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201322021
• Languages: English
• ISSNs: 0931-7597

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>K₈Na₁₀{ [Mn^IV₂Mn^III₆Mn ^II₄(μ₃‐O)₆ (μ‐OH)₄(H₂O)₂ (CO₃)₆] [B‐β‐SiW₆O₂₆] ₂}·30H₂O is synthesized from an aqueous mixture of K₈[β₂‐SiW₁₁O₃₉], MnCl₂, NaCl, 2, 3‐pyrazinedicarboxylic acid, and K₂CO₃ (pH 10.2, 50 °C, 5 h, 38% yield).</p> </abstract>