<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>PdCl<sub>2</sub>/CuCO<sub>3</sub>‐mediated treatment of biaryl‐2‐amines with various alkenes like (II) and (VII) is found to allow a new, regio‐ and chemoselective access to phenanthridine derivatives.</p> </abstract>