<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Single‐crystalline Sb<sub>2</sub>Te<sub>3</sub> nanosheets are prepared by a simple template‐free solvothermal approach using SbCl<sub>3</sub>, Na<sub>2</sub>TeO<sub>3</sub>, N<sub>2</sub>H<sub>4</sub>·H<sub>2</sub>O, and NH<sub>3</sub> in ethylene glycol (autoclave, 473 K, 12 h).</p> </abstract>