Graphene Nanoplatelets: Electrochemical Properties and Applications for Oxidation of Endocrine‐Disrupting Chemicals. Issue 10 (23rd January 2013)

• Record Type: Journal Article
• Authors: Wan, Qijin; Cai, Hui; Liu, Yi; Song, Hongtu; Liao, Hualing; Liu, Shantang; Yang, Nianjun
• Is Part Of: Chemistry. Volume 19:Issue 10(2013)
• Page Start: 3483
• Page End: 3489
• Publication Date: 2013-01-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201203607
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>In most graphene‐based electrochemical applications, graphene nanoplatelets (GNPs) have been applied. Now, for the first time, electrochemical properties of GNPs, namely, its electrochemical activity, potential window, and double‐layer capacitance, have been investigated. These properties are compared with those of carbon nanotubes (CNTs). GNP‐ and CNT‐coated electrodes were then applied for electrochemical oxidation of endocrine‐disrupting chemicals. The GNP‐coated electrode was characterized by atomic force microscopy and electrochemical techniques. Compared with the CNT‐coated electrode, higher peak current for the oxidation of 4‐nonylphenol is achieved on the GNP‐coated electrode, together with lower capacitive current. Electrochemical oxidation of 2, 4‐dichlorophenol, bisphenol A, and octylphenol in the absence or presence of 4‐nonylphenol was studied on the GNP‐coated electrode. The results suggest that GNPs have better electrochemical performance than CNTs and are thus more promising for electrochemical applications, for example, electrochemical detection and removal of endocrine‐disrupting chemicals.</p> </abstract>