Single‐Crystalline‐Phase Mo3VOx: An Efficient Catalyst for the Partial Oxidation of Acrolein to Acrylic Acid. Issue 10 (21st June 2013)

• Record Type: Journal Article
• Authors: Chen, Chen; Kosuke, Nakatani; Murayama, Toru; Ueda, Wataru
• Is Part Of: ChemCatChem. Volume 5:Issue 10(2013:Oct.)
• Page Start: 2869
• Page End: 2873
• Publication Date: 2013-06-21
• Subjects: Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201300268
• Languages: English
• ISSNs: 1867-3880

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Being single (crystalline):</bold> Four single‐crystalline‐phase Mo₃VO_{<italic>x</italic>} materials are utilized as catalysts for the partial oxidation of acrolein to acrylic acid. The crystalline structure has a clear effect on catalytic performance. Mo₃VO_{<italic>x</italic>} with a trigonal crystalline structure is the most efficient catalyst: 99.8 % conversion with 93.9 % selectivity for acrylic acid is obtained at a temperature (217.3 °C) much lower than that previously reported.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg3hdxx9v8" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>