Model C sp 2C sp 3 Hurtley Coupling Catalysis that Operates through a Well‐Defined CuI/CuIII Mechanism. Issue 3 (19th February 2013)

• Record Type: Journal Article
• Authors: Rovira, Mireia; Font, Marc; Ribas, Xavi
• Is Part Of: ChemCatChem. Volume 5:Issue 3(2013:Mar.)
• Page Start: 687
• Page End: 691
• Publication Date: 2013-02-19
• Subjects: Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201200885
• Languages: English
• ISSNs: 1867-3880

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>The Hurtley locker:</bold> The first examples of copper‐catalyzed C<mml:math overflow="scroll" xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mtext> </mml:mtext><mml:mrow><mml:mtext>sp</mml:mtext><mml:msup><mml:mtext> </mml:mtext><mml:mrow><mml:mtext>2</mml:mtext></mml:mrow></mml:msup></mml:mrow></mml:msub></mml:math><inline-graphic xlink:href="ark:/27927/pgg36pz0fsj" mimetype="image" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />C<mml:math overflow="scroll" xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mtext> </mml:mtext><mml:mrow><mml:mtext>sp</mml:mtext><mml:msup><mml:mtext> </mml:mtext><mml:mrow><mml:mtext>3</mml:mtext></mml:mrow></mml:msup></mml:mrow></mml:msub></mml:math><inline-graphic xlink:href="ark:/27927/pgg36pz0fgk" mimetype="image" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> cross‐coupling with the direct involvement of a Cu^I/Cu^III catalytic cycle are reported. The product rapidly reorganizes into a 1, 2‐dihydroisoquinoline scaffold.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36pz0dnt" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>