Catalytic Dehydrogenative Amide and Ester Formation with Rhenium–Triphos Complexes. Issue 7 (11th April 2013)

• Record Type: Journal Article
• Authors: Schleker, P. Philipp M.; Honeker, Roman; Klankermayer, Jürgen; Leitner, Walter
• Is Part Of: ChemCatChem. Volume 5:Issue 7(2013:Jul.)
• Page Start: 1762
• Page End: 1764
• Publication Date: 2013-04-11
• Subjects: Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201200942
• Languages: English
• ISSNs: 1867-3880

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>[Re]ad all about it:</bold> The first examples of the rhenium‐catalyzed dehydrogenative formation of amides and esters with the highly active ReH₅(triphos) complex are demonstrated. The addition of a tertiary amine additive improves the selectivity and the stability of the catalyst in the formation of esters from primary alcohols.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg22f4znp0" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>