Preparation of water‐compatible molecularly imprinted polymers for caffeine with a novel ionic liquid as a functional monomer. Issue 4 (17th May 2012)

• Record Type: Journal Article
• Authors: Luo, Xubiao; Dong, Ruizhi; Luo, Shenglian; Zhan, Youcai; Tu, Xinman; Yang, Lixia
• Is Part Of: Journal of applied polymer science. Volume 127:Issue 4(2013:Feb. 15)
• Page Start: 2884
• Page End: 2890
• Publication Date: 2012-05-17
• Subjects: Polymers -- Periodicals; Polymerization -- Periodicals; 668.9
• DOI: 10.1002/app.36792
• Languages: English
• ISSNs: 0021-8995

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Water‐compatible molecularly imprinted polymers (MIPs) for caffeine were synthesized in aqueous medium with a new functional monomer, 1‐(α‐methyl acrylate)‐3‐methylimidazolium bromide (1‐MA‐3MI‐Br), which had π–π and hydrogen‐bonding interactions. Caffeine‐imprinted polymers were prepared in suspension polymerization with 1‐MA‐3MI‐Br and methacrylic acid (MAA), which only had hydrogen bonding, as a functional monomer. For the specific binding characteristics of the new functional monomer 1‐MA‐3MI‐Br, the adsorption capacity and relative separation factor (β) of MIPs for caffeine were significantly enhanced. The maximum adsorption capacities of 1‐MA‐3MI‐Br–MIP and MAA–MIP imprinted microspheres for caffeine were 53.80 and 28.90 μmol/g, respectively. Moreover, the relative separation factors were measured by comparison of the separation characteristics under competitive adsorption conditions. The results showed that the β of MAA–MIP for caffeine relative to theophylline was only 1.65; this showed a very poor recognition selectivity for caffeine, but β of 1‐MA‐3MI‐Br–MIP for caffeine with respect to theophylline was remarkably enhanced to 3.19; this showed an excellent recognition selectivity and binding affinity toward caffeine molecules in an aqueous environment. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013</p> </abstract>