ChemInform Abstract: Microwave‐Assisted Carbohydrohalogenation of First‐Row Transition‐Metal Oxides (M: V, Cr, Mn, Fe, Co, Ni, Cu) with the Formation of Element Halides. Issue 1 (7th January 2014) - Berger, Matthias
Abstract Anhydrous transition metal chlorides and bromides MyXz (M: V, Cr, Mn, Fe, Co, Ni, Cu; X: Cl, Br) are synthesized in quantitative yields in a one‐step reaction of the metal oxides, graphite, and flowing HX under microwave irradiation (quartz‐tubes, 1000—1400 °C, 15 min).