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ChemInform Abstract: Ring‐Expansion Reaction of Isatins with Ethyl Diazoacetate Catalyzed by Dirhodium(II)/DBU Metal‐Organic System: En Route to Viridication Alkaloids. Issue 11 (18th March 2014)
Record Type:
Journal Article
Title:
ChemInform Abstract: Ring‐Expansion Reaction of Isatins with Ethyl Diazoacetate Catalyzed by Dirhodium(II)/DBU Metal‐Organic System: En Route to Viridication Alkaloids. Issue 11 (18th March 2014)
Main Title:
ChemInform Abstract: Ring‐Expansion Reaction of Isatins with Ethyl Diazoacetate Catalyzed by Dirhodium(II)/DBU Metal‐Organic System: En Route to Viridication Alkaloids.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A sequential process for the Eistert ring expansion of isatins with ethyl diazoacetate is developed consisting of a DBU‐promoted addition of the diazoester to the isatin 3‐carboxy group followed by Rh(II)‐catalyzed diazo decomposition of the isatin diazo intermediate.</p> </abstract>