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ChemInform Abstract: Et3B‐Mediated Radical‐Polar Crossover Reaction for Single‐Step Coupling of O, Te‐Acetal, α, β‐Unsaturated Ketones, and Aldehydes/Ketones. Issue 8 (25th February 2014)
Record Type:
Journal Article
Title:
ChemInform Abstract: Et3B‐Mediated Radical‐Polar Crossover Reaction for Single‐Step Coupling of O, Te‐Acetal, α, β‐Unsaturated Ketones, and Aldehydes/Ketones. Issue 8 (25th February 2014)
Main Title:
ChemInform Abstract: Et3B‐Mediated Radical‐Polar Crossover Reaction for Single‐Step Coupling of O, Te‐Acetal, α, β‐Unsaturated Ketones, and Aldehydes/Ketones.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The mixed O, Te‐acetal (I) derived from 2, 4, 10‐trioxaadamantane reacts with cyclic α, β‐unsaturated ketones (II) under Et<sub>3</sub>B/O<sub>2</sub>‐mediated radical conditions to form the β‐adducts (III).</p> </abstract>