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ChemInform Abstract: Strain‐Promoted Retro‐Dieckmann‐Type Condensation on [2.2.2]‐ and [2.2.1]Bicyclic Systems: A Fragmentation Reaction for the Preparation of Functionalized Heterocycles and Carbocycles. Issue 6 (11th February 2014)
Record Type:
Journal Article
Title:
ChemInform Abstract: Strain‐Promoted Retro‐Dieckmann‐Type Condensation on [2.2.2]‐ and [2.2.1]Bicyclic Systems: A Fragmentation Reaction for the Preparation of Functionalized Heterocycles and Carbocycles. Issue 6 (11th February 2014)
Main Title:
ChemInform Abstract: Strain‐Promoted Retro‐Dieckmann‐Type Condensation on [2.2.2]‐ and [2.2.1]Bicyclic Systems: A Fragmentation Reaction for the Preparation of Functionalized Heterocycles and Carbocycles.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The ring strain of (7‐hetero)norbornene and (7‐hetero)norbornane systems is exploited in the opening of (7‐hetero)bicyclic skeletons containing a β‐ketosulfone/ester functionality through a retro‐Dieckmann type reaction.</p> </abstract>