A three‐dimensional chiral crystal structure constructed from a chiral triazolate ligand showing an SrSi2 topology: poly[bis(μ3‐3, 5‐diethyl‐1, 2, 4‐triazolato‐κ3N1:N2:N4)trisilver nitrate]. (12th November 2013)

• Record Type: Journal Article
• Authors: Jiang, Feng; Dai, Lin; Shi, Yiqiang; Wang, Zhixiang
• Is Part Of: Acta crystallographica. Volume 69:Part 12(2013:Dec.)
• Page Start: 1485
• Page End: 1487
• Publication Date: 2013-11-12
• Subjects: Crystallography -- Periodicals; Crystals -- Periodicals; 548.05
• DOI: 10.1107/S0108270113029788
• Languages: English
• ISSNs: 0108-2701

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>In the title metal–organic framework (MOF), {[Ag₃(C₆H₁₀N₃)₂]NO₃}_{<italic>n</italic>}, the Ag^I cation is coordinated by two N atoms from two different 3, 5‐diethyl‐1, 2, 4‐triazolate (detz) ligands in a linear configuration. Each Ag^I cation is then connected to two adjacent Ag^I cations <italic>via</italic> a μ₃‐<italic>N</italic>¹:<italic>N</italic>²:<italic>N</italic>⁴‐detrz ligand, resulting in a three‐dimensional chiral silver–triazolate structure showing an SrSi₂ (<bold>srs</bold>) net with 10³ topology.</p> </abstract>