Monophosphate tungsten bronzes with pentagonal tunnels: reinvestigation through the peephole of the superspace. (26th February 2013)

• Record Type: Journal Article
• Authors: Pérez, Olivier; Elcoro, Luis; Pérez‐Mato, J. M.; Petříček, Václav
• Is Part Of: Acta crystallographica. Volume 69:Part 2(2013:Apr.)
• Page Start: 122
• Page End: 136
• Publication Date: 2013-02-26
• Subjects: Crystallography -- Periodicals; Crystallization -- Periodicals; Chemical structure -- Periodicals; Solid state physics -- Periodicals; 530.41105
• DOI: 10.1107/S0108768113002826
• Languages: English
• ISSNs: 0108-7681

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The large family of monophosphate tungsten bronzes with pentagonal tunnels (MPTBp), (PO₂)₄(WO₃)_{2<italic>m</italic>} with <italic>m</italic> ranging from 4 to 14, can be considered as modular structures <italic>via</italic> a description with (PO₂)₂(WO₃)_{<italic>m</italic>} modules related together by a symmetry operation and alternating along the <italic>z</italic> axis. Following the success of the application of the superspace for the description of the lillianites homologous series, a (3 + 1)‐dimensional superspace model is efficiently defined to unify the structural analysis of the MPTBp. The (3 + 1)‐dimensional model reveals hidden common characteristics such as the symmetry. An evaluation of the model for six well known members of the series was carried out from experimental data collected to this aim.</p> </abstract>