[Bis(3, 5‐diisopropylpyrazol‐1‐yl‐κN2)dihydroborato](triphenylphosphane‐κP)copper(I). (5th August 2013)

• Record Type: Journal Article
• Authors: Fujisawa, Kiyoshi; Noguchi, Naoto; Noguchi, Yuki; Lehnert, Nicolai
• Is Part Of: Acta crystallographica. Volume 69:Part 9(2013:Sep.)
• Page Start: 943
• Page End: 946
• Publication Date: 2013-08-05
• Subjects: Crystallography -- Periodicals; Crystals -- Periodicals; 548.05
• DOI: 10.1107/S0108270113015965
• Languages: English
• ISSNs: 0108-2701

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>In the title compound, [Cu(C₁₈H₃₂BN₄)(C₁₈H₁₅P)], the Cu^I ion is coordinated by two N atoms from the anionic bidentate chelating bis(3, 5‐diisopropylpyrazol‐1‐yl)dihydroborate ligand [average Cu—N distance = 1.994 (3) Å] and the P atom from a triphenylphosphane ligand [Cu—P distance = 2.1676 (8) Å] in a trigonal geometry [the sum of the angles around the Cu^I atom is 359.6 (1)°]. The N—Cu—N angle between adjacent coordinated pyrazole‐ring N atoms is 98.99 (9)°, while the average N—Cu—P angle between the coordinated pyrazole N atom and the triphenylphosphane P atom is 130.3 (1)°.</p> </abstract>