Magnesium isotopic fractionation in chondrules from the Murchison and Murray CM2 carbonaceous chondrites. (12th February 2013)

• Record Type: Journal Article
• Authors: Bouvier, Audrey; Wadhwa, Meenakshi; Simon, Steven B.; Grossman, Lawrence
• Is Part Of: Meteoritics & planetary science. Volume 48:Number 3(2013:Mar.)
• Page Start: 339
• Page End: 353
• Publication Date: 2013-02-12
• Subjects: Meteorites -- Periodicals; Planetology -- Periodicals; 523.4
• DOI: 10.1111/maps.12059
• Languages: English
• ISSNs: 1086-9379

Abstract

<abstract abstract-type="main" xml:lang="en" id="maps12059-abs-0001"> <title>Abstract</title> <p>We present high‐precision measurements of the Mg isotopic compositions of a suite of types I and II chondrules separated from the Murchison and Murray CM2 carbonaceous chondrites. These chondrules are olivine‐ and pyroxene‐rich and have low <sup>27</sup>Al/<sup>24</sup>Mg ratios (0.012–0.316). The Mg isotopic compositions of Murray chondrules are on average lighter (δ<sup>26</sup>Mg ranging from −0.95‰ to −0.15‰ relative to the DSM‐3 standard) than those of Murchison (δ<sup>26</sup>Mg ranging from −1.27‰ to +0.77‰). Taken together, the CM2 chondrules exhibit a narrower range of Mg isotopic compositions than those from CV and CB chondrites studied previously. The least‐altered CM2 chondrules are on average lighter (average δ<sup>26</sup>Mg = −0.39 ± 0.30‰, 2SE) than the moderately to heavily altered CM2 chondrules (average δ<sup>26</sup>Mg = −0.11 ± 0.21‰, 2SE). The compositions of CM2 chondrules are consistent with isotopic fractionation toward heavy Mg being associated with the formation of secondary silicate phases on the CM2 parent body, but were also probably affected by volatilization and recondensation processes involved in their original formation. The low‐Al CM2 chondrules analyzed here do not exhibit any mass‐independent variations in <sup>26</sup>Mg from the decay of <sup>26</sup>Al, with the exception of two chondrules that show only small variations just outside of the analytical error. In the case of the chondrule with the highest Al/Mg ratio (a type IAB chondrule from Murchison), the lack of resolvable <sup>26</sup>Mg excess suggests that it either formed >1 Ma after calcium‐aluminum‐rich inclusions, or that its Al‐Mg isotope systematics were reset by secondary alteration processes on the CM2 chondrite parent body after the decay of <sup>26</sup>Al.</p> </abstract>